I'm sure it was said somewhere in the story, b it also the fact that their characters are made to be polar opposites. The color schemes, the moods and even the names. Loona, like the name suggests, is very lunar themes, and Sol, short for Solar, is very solar themed. They also act very different with Loona being confident and abrasive, and Sol being timid and apologetic
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Millie feeling a little depressed because of loona comes across loonas sister, both of them chat which ends with them going into a magic shop in which millie hopes to get a item which allowes her to disguise as loona and make sure loona isnt having sex with her partner.
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i just wanna see Sol get nutted in